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Bespring Chemical

Food grade phosphate · Solid TKPP · INS 450(v) / E450(v)

Food Grade Tetrapotassium Pyrophosphate (TKPP)

Bespring supplies food grade tetrapotassium pyrophosphate (TKPP), a solid alkaline potassium phosphate evaluated in meat, seafood and processed-cheese systems. Specify the food standard, assay basis, fluoride limit and powder or granular form before selecting a grade for your process.

CAS number
7320-34-5
INS number
450(v)
Formula
K4P2O7
Reference MOQ*
500 kg
Food grade TKPP bag labelled tetrapotassium pyrophosphate and 25 kg
TKPP bag labelled 25 kg; packaging reference. Confirm the shipment label and final packing in the quotation.

Product illustration · grade and packaging specified in your offer

*Confirm current order terms. Include application, destination, required standard, critical impurity limits and quantity. See the commercial fluoride-limit comparison below.

Reference assayK₄P₂O₇ content ≥ 95.0%

Reference packing25 kg bag

Container loadingReference: 20 MT / 20' FCL

Document supportRequest grade-specific COA, TDS, SDS and certificate scope

Product overview

What is tetrapotassium pyrophosphate?

Tetrapotassium pyrophosphate (TKPP), also called tetrapotassium diphosphate or potassium pyrophosphate, is the potassium salt of pyrophosphoric acid. Its chemical formula is K4P2O7, its CAS number is 7320-34-5, and its food additive identity is INS 450(v) / E450(v). This page describes solid TKPP with the anhydrous formula shown, not a liquid solution or a specified hydrate.

TKPP is hygroscopic and soluble in water. The JECFA TKPP monograph identifies emulsifier and texturizer functions. Its formula weight is 330.34 g/mol. Confirm the offered grade’s form and reporting basis; absorbed moisture is not evidence of a defined crystalline hydrate. Food qualification requires the relevant specification and documents, rather than chemical identity alone.

Procurement snapshot

Product name
Tetrapotassium pyrophosphate
Common abbreviation
TKPP
Category
Potassium phosphate salt
Appearance
White powder or granules
Reference MOQ
500 kg
Standard packing
25 kg / bag

Potassium-based phosphate decision

When should a formulator evaluate TKPP?

Evaluate TKPP when potassium-based pyrophosphate functionality addresses a defined formulation requirement. Compare sodium and potassium contribution, solution behavior and measured finished-food performance with the current phosphate system.

01

Sodium contribution

The K₄P₂O₇ formula contains no sodium; sodium impurities in the offered grade need separate confirmation, so it may be screened against TSPP in sodium-reduction work. This does not make the finished food “low sodium”; calculate every sodium source and verify the legal claim criteria.

02

Potassium load

Pure anhydrous K4P2O7 is theoretically about 47.4% potassium by mass. This formula calculation is not a batch assay. Request composition data for the offered grade and distinguish elemental K and P from K₂O or P₂O₅ reporting.

03

Alkalinity and flavor

JECFA gives pH 10.0–10.7 for a 1 in 100 solution. This is a standard reference, not a grade-specific commercial pH guarantee or the final food pH. Measure the complete formulation and assess flavor, color and texture under the intended process.

04

Dissolution environment

Although TKPP is water-soluble, practical dissolution depends on concentration, temperature, water hardness, agitation, salt content and ingredient order. Check clarity and sediment in the actual brine or process water.

Claim boundary: replacing a sodium phosphate with TKPP can reduce sodium contributed by that ingredient, but nutritional claims require a calculation for the complete finished food and the destination market.

Functional roles

Why is TKPP used in food processing?

The FDA potassium pyrophosphate inventory lists emulsifier/emulsifier-salt and texturizer effects, consistent with the JECFA monograph. These functions describe the ingredient; they do not establish performance or permission for every food.

Function 01

Mineral and pH management

Pyrophosphate can interact with polyvalent ions such as calcium. TKPP also gives an alkaline aqueous solution. Sequestration and pH adjustment are distinct effects; evaluate mineral balance, protein behavior, clarity and sediment separately in the complete system.

  • Metal-ion sequestration
  • Check water hardness and calcium load
  • Measure solution and finished-product pH

Function 02

Protein and emulsion functionality

In suitable meat or cheese systems, an alkaline phosphate system can support protein hydration and fat–water stabilization. Raw material, salt, shear, temperature and total phosphate determine the result.

  • Emulsifier and texturizer functionality
  • Protein extraction and hydration screening
  • Cook loss, purge and texture validation

Food industry uses

Common food grade TKPP applications

Use these application areas to define a trial brief, then confirm the exact food category and permitted use in the destination market. A reference specification does not predict retained yield, texture or storage stability.

Meat and poultry brines

Compare TKPP within a phosphate system when sodium contribution, protein extraction, water binding or emulsion stability is under review. Record brine clarity, pickup, cook loss, chilled purge, texture and sensory quality.

Processed cheese systems

Screen calcium sequestration, casein hydration and fat–water emulsification. Control natural-cheese composition, calcium, moisture, pH, heating, shear and cooling before judging slice or spread texture.

Seafood processing

Where permitted, compare TKPP or a phosphate blend for solution behavior and retained yield. Measure pickup after equal drainage, thaw/cook loss, texture and retained phosphate where required. Follow the TKPP frozen-seafood trial guide for species and process variables.

Potassium-based phosphate blends

Use TKPP as one component only when its alkalinity and pyrophosphate functionality help meet a defined sodium, solubility or performance target. Validate blend compatibility and storage stability.

Technical information

Food grade TKPP reference specification

These commercial reference limits are separate from batch COA results and do not establish conformity to every international compendium. Agree the current specification and test methods before ordering. For mass-based reporting, 1 ppm = 1 mg/kg; the commercial 0.003% fluoride value is 30 mg/kg, not 3 mg/kg.

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Tetrapotassium pyrophosphate (TKPP) — commercial reference limits
Test itemUnitCommercial limitPurchasing requirements
K₄P₂O₇ content%≥ 95.0Commercial basis/method unconfirmed; JECFA ≥95% is on the ignited basis
Water-insoluble matter%≤ 0.2Same numerical limit as JECFA; confirm the method and lot result
Arsenic (As)mg/kg≤ 3JECFA ≤3; published EU E450(v) text ≤1. Confirm separate As testing
Heavy metals (as Pb)mg/kg≤ 10Aggregate “as Pb” test; does not replace Pb, As, Cd or Hg results
Lead (Pb)mg/kg≤ 2JECFA ≤4; published EU E450(v) text ≤1. Confirm separate Pb testing
Fluoride (F)mg/kg≤ 30JECFA and published EU E450(v) text ≤10; commercial limit cannot guarantee this
“Loss on ignition at 110°C”%≤ 0.5Temperature and method require agreement; equivalence to JECFA LOI is not established
Cadmium (Cd)mg/kg≤ 1Commercial limit; confirm element-specific method and batch result
Mercury (Hg)mg/kg≤ 1Commercial limit; confirm element-specific method and batch result
Appearance—White powder or granulesConfirm offered powder/granular form and particle distribution

Specification decision: The commercial fluoride maximum is 30 mg/kg, compared with 10 mg/kg in JECFA and the published EU E450(v) text. That limit cannot guarantee either requirement, although an individual batch may test lower. Published EU arsenic and lead maxima are each 1 mg/kg, below the commercial 3 and 2 mg/kg limits. Request an aligned specification, methods and batch COA; matching selected limits does not establish full conformity.

Test-basis distinction: The commercial reference is “Loss on ignition at 110°C” ≤0.5%. JECFA ignition loss is ≤2% using 105°C for 4 hours, then 550°C for 30 minutes. The commercial label does not establish that method and must not be treated as a loss-on-drying result. Assay, ignition loss and P₂O₅ are separate measurements.

JECFA identity and specification

JECFA lists INS 450(v), CAS 7320-34-5, formula K4P2O7, formula weight 330.34 g/mol, assay ≥95% on the ignited basis and pH 10.0–10.7 for a 1 in 100 solution.

Review the JECFA monograph

Avoid phosphate-name confusion

TKPP vs. TSPP and KTPP

These materials are not interchangeable by acronym or equal weight. Compare the ion, phosphate chain, alkalinity, solubility, legal identity and validated function.

TKPP

K4P2O7 · INS 450(v)

Potassium pyrophosphate; consider when potassium-based, alkaline pyrophosphate functionality is required.

TSPP

Na4P2O7 · INS 450(iii)

Sodium pyrophosphate; compare sodium contribution, practical dissolution and equivalent functional performance.

Review food grade TSPP

KTPP

K5P3O10

Potassium tripolyphosphate has a different phosphate chain and specification. Do not treat the similar abbreviation as the same ingredient.

Review food grade KTPP

Qualification support

Documents to request before approval

Certificates and management-system documents are time-sensitive. Ask for current, applicable copies and verify the product name, site, scope, issuer and validity dates during supplier qualification.

Product documents

Current specification, technical data sheet, safety data sheet and a representative or batch-specific certificate of analysis.

Food-grade selection requirements

State any HACCP, Kosher, Halal, allergen or source-document requirements. Confirm availability and current coverage for the exact offered product and production or packing site.

Management systems

Request the current ISO certificate and scope, together with traceability or quality questionnaires. A company or sales-service certificate does not automatically cover the product, manufacturing site or batch.

Storage & handling

Protect TKPP from moisture and heat

  • Control temperatureStore in a cool place; use the stated storage temperature not exceeding 30°C.
  • Keep packaging sealedTKPP is hygroscopic. Protect it from humidity, direct sunlight and contamination. Ask for the offered grade’s shelf life and opened-bag instructions; no shelf-life period is specified here.
  • Follow the SDSUse appropriate workplace controls and personal protective equipment for dust handling.

Appearance and handling references

TKPP sample and warehouse references

White powder in a glass dish labelled tetrapotassium pyrophosphate TKPP
Powder appearance reference
Unmarked paper bags stacked on pallets in a warehouse
Warehouse handling referenceUnmarked bags; contents and lot cannot be identified from this view. Confirm pallet layout and final loading for the shipment.

Application approval

Run a controlled TKPP comparison

A potassium-phosphate substitution should be approved from measured product and process results, not only a nutrition calculation.

  1. 1

    Define the baseline

    Record current phosphate, sodium and potassium sources, water chemistry, formula pH, process loss and target claim.

  2. 2

    Prepare the solution

    Add TKPP gradually under agitation and record temperature, concentration, ingredient order, dissolution time, clarity and sediment.

  3. 3

    Compare equal conditions

    Hold raw material, salt, water, shear, temperature, processing and sampling constant against the approved control.

  4. 4

    Approve the complete result

    Assess finished pH, sodium/potassium calculation, yield, purge, emulsion or texture, flavor, storage stability and legal labeling.

Buyer questions

Food grade TKPP FAQ

Why is TKPP evaluated instead of TSPP?

TKPP supplies potassium rather than the sodium supplied by TSPP. Compare the full formula’s sodium and potassium contribution, pH, dissolution, flavor and process results. An equal-weight substitution or a finished-food low-sodium claim must not be assumed.

Is TKPP the same as tetrapotassium diphosphate?

Yes. Tetrapotassium pyrophosphate, tetrapotassium diphosphate and potassium pyrophosphate identify K₄P₂O₇, CAS 7320-34-5, INS 450(v) / E450(v). This page describes the solid material; a liquid solution requires a separately specified concentration.

Does TKPP make a finished food low sodium?

No. Its chemical formula contains no sodium, but the offered grade may have impurities and the food contains other sodium sources. Use supported composition data for the complete finished food and verify destination-market claim criteria.

What must be checked before dissolving TKPP?

Specify the offered powder or granular form, water temperature and hardness, target concentration, agitation, salt/mineral content and ingredient order. Measure dissolution time, clarity, sediment and solution pH in the actual process water or brine.

Does the supplied specification meet JECFA or EU limits?

It cannot guarantee conformity. The fluoride limit is 30 mg/kg, compared with 10 mg/kg in JECFA and the published EU E450(v) text. The published EU arsenic and lead limits are also lower. A batch may test below the commercial maximum; request an aligned specification, confirmed methods and a batch COA, and check the current applicable standard.

What details are needed for an accurate TKPP quotation?

Provide solid food grade TKPP, powder/granular preference, application and process, destination market, required standard, assay basis, fluoride and other critical limits, quantity, packaging, port, Incoterm and delivery requirements. List the TDS, SDS, COA and declarations needed for approval.

Is food grade TKPP interchangeable with technical or fertilizer grade?

No. The chemical name and CAS do not establish food qualification. Impurity controls, intended use, documentation and applicable rules differ. Specify food grade and the required standard; do not qualify a technical, fertilizer or liquid product from identity alone.

Is the 110°C loss value the same as JECFA loss on ignition?

No equivalence is established. The commercial reference states “Loss on ignition at 110°C” ≤0.5%, while JECFA uses 105°C for 4 hours followed by 550°C for 30 minutes, with a ≤2% limit. Agree the analytical method and reporting basis; do not rename the commercial result loss on drying.

Continue the decision

Related phosphate and application resources

Tetrasodium Pyrophosphate

Compare the sodium analogue by ion contribution, solution behavior and validated application performance.

Food Phosphate Blends

Consider a defined blend where alkalinity, solubility and functional timing must be balanced.

Start a sourcing conversation

Request a food grade TKPP quote

Share the details that affect technical fit, documentation and landed cost. Our team can then prepare a relevant commercial response.

  • Application and current phosphate benchmark
  • Sodium/potassium target and destination market
  • pH, solubility, particle and impurity limits
  • Quantity, packing, port, Incoterm and documents

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Form & analytics information

Product documents

Request documents

Tell us your grade and destination market so we can confirm which documents are available for your order.

An external reference is not a batch certificate or a Bespring product specification.