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Food grade acidic orthophosphate · E340(i) / INS 340(i)

Food Grade Monopotassium Phosphate (MKP)

Source food grade MKP for acidic phosphate buffering, controlled potassium and phosphorus input, and qualified fermentation or dry-food systems. Keep it separate from fertilizer-grade 0-52-34 MKP.

CAS number
7778-77-0
Formula
KH2PO4
1% solution pH
4.2–4.7
Reference MOQ
500 kg

Include the target pH, mineral basis, food standard, application, quantity and destination.

Food grade phosphate ingredient samples
Reference assayKH2PO4 ≥98.0% on dry basis
Standard packing25 kg bag
Container loadingReference: 23 MT / 20' FCL
Food-grade reviewCOA and applicable certificates on request

Product identity

What is food grade monopotassium phosphate?

Monopotassium phosphate (MKP), also called potassium dihydrogen phosphate or monobasic potassium phosphate, is the acidic potassium orthophosphate KH2PO4. JECFA identifies it as INS 340(i), CAS 7778-77-0, with buffer, neutralizing-agent, sequestrant and yeast-food functions.

JECFA describes it as freely soluble in water with a pH of 4.2–4.7 for a 1% solution. It supplies potassium and phosphorus but does not provide sodium; any mineral or nutrition declaration must use the offered grade's certified composition and the complete finished-food formula.

The critical search and procurement boundary

Food grade MKP is not fertilizer MKP 0-52-34

The same chemical name and CAS appear in food and agricultural markets, but intended use, guaranteed analysis, impurity controls, manufacturing/packing scope and documentation are not interchangeable.

Food ingredient intent

Food grade MKP E340(i)

  • Food-additive identity and destination-market review
  • Assay, pH, insolubles and elemental impurities
  • Food-contact packing, traceability and applicable documents
  • Performance in the actual food or fermentation system
Agricultural intent

Fertilizer MKP 0-52-34

  • N-P-K guaranteed analysis and crop application
  • Water-soluble fertilizer and fertigation requirements
  • Agricultural registration and contaminant rules
  • Not approved for food merely because the formula is KH2PO4
Go to the MKP fertilizer page

Receiving control: require the label, lot number, signed specification and COA to identify the food-grade supply. Do not approve material using an agricultural NPK certificate.

Application-specific screening

Where food grade MKP is evaluated

These are technical evaluation paths, not universal permissions or dosage guidance. Confirm the food category, total phosphate, mineral declaration and destination-market rules.

Beverage and electrolyte dry mixes

Evaluate MKP when a soluble potassium/phosphate input and acidic buffer profile are required. Check reconstitution pH, mineral taste, clarity, sediment, compatibility with calcium/magnesium and declared nutrition.

Food fermentation and cultures

Use as a candidate phosphate/potassium source and buffer only after defining organism, medium composition and target pH. Track growth, acidification, yield, by-products and downstream purification.

Nutrition powders and premixes

Calculate potassium and phosphorus from certified composition, then test particle-size compatibility, blend segregation, dissolution, caking, sensory impact and label limits.

Acidic phosphate buffer systems

Pairing MKP with a more alkaline potassium phosphate such as DKP can broaden pH adjustment options. Determine the ratio experimentally in the real ionic and temperature environment.

Commercial data with method boundaries

Food grade MKP reference specification

The values reproduce Bespring's supplied product sheet. They are not a batch COA or evidence of universal compendial compliance. Confirm units, methods and the signed food-grade specification before approval.

Monopotassium phosphate — supplied reference limits
Test itemUnitSupplied limitQualification note
KH2PO4 assay, dry basis%≥98.0Matches JECFA minimum
Fluoride (F)mg/kg≤10Matches JECFA maximum
Heavy metals (as Pb)mg/kg≤10Not the same test as lead
“Loss on ignition”%≤0.5Source method absent; JECFA specifies loss on drying, not LOI
Water-insoluble matter%≤0.1Stricter than JECFA 0.2%
Arsenic (As)mg/kg≤3Matches JECFA maximum
Cadmium (Cd)mg/kg≤1Supplied commercial parameter
Mercury (Hg)mg/kg≤1Supplied commercial parameter
Lead (Pb)mg/kg≤5Does not meet JECFA 4 mg/kg maximum

Specification decision: the supplied lead limit of 5 mg/kg is above JECFA's 4 mg/kg maximum. The sheet also omits pH, appearance, identity, solubility and a defined loss-on-drying method. Do not claim JECFA conformity without an offered grade and COA that meet the full standard.

JECFA reference

INS 340(i); assay ≥98% after drying; pH 4.2–4.7 (1%); loss on drying ≤2% at 105°C for 4 h; insolubles ≤0.2%; F ≤10, As ≤3 and Pb ≤4 mg/kg.

Review the JECFA MKP monograph

Missing purchasing fields

Request pH, potassium/phosphorus or K2O/P2O5 reporting basis where needed, solution clarity, chloride/sulfate/sodium, particle size, bulk density, moisture method and shelf life.

Choose the phosphate species

MKP vs. DKP and phosphoric acid

Selection begins with target pH and ion contribution, not with the shared word “potassium.” Equal-weight substitution changes potassium, phosphorus and acid/base balance.

MKP · KH2PO4

Acidic potassium orthophosphate

Use as a candidate where acidic phosphate buffering and potassium/phosphorus input are required. JECFA 1% pH: 4.2–4.7.

DKP · K2HPO4

More alkaline potassium orthophosphate

Compare when a higher pH response or different potassium-to-phosphate ratio is required. A controlled MKP/DKP ratio can be evaluated as a buffer pair.

Phosphoric acid · H3PO4

Acidulant without potassium input

Compare when acidification is the primary goal and added potassium is not desired. Handling, concentration and corrosion controls differ.

Theoretical composition for preliminary calculationsPure anhydrous KH2PO4 contains approximately 28.7% potassium and 22.8% phosphorus by mass. Use certified batch composition—not theoretical purity—for labels and commercial formulation.

Application approval

How to qualify food grade MKP

Connect the exact food-grade source to solution behavior, mineral balance, process response and destination-market rules.

  1. 1

    Fix the target

    State the food or fermentation process, target pH, potassium/phosphorus contribution, total phosphate and mandatory label or impurity limits.

  2. 2

    Verify the grade

    Match identity, food-grade standard, methods, traceability, current specification, TDS, SDS and COA. Review certificates only for the offered product/site and validity period.

  3. 3

    Test solution behavior

    Record water chemistry, temperature, concentration, ingredient order, dissolution time, clarity, sediment and measured pH.

  4. 4

    Validate the end use

    For beverages or powders assess taste, clarity and stability; for cultures assess growth, acidification, yield and downstream effects under matched conditions.

Storage and handling

Keep MKP cool, dry and sealed

  • TemperatureThe supplied guidance states storage at no more than 30°C.
  • EnvironmentProtect sealed bags from direct sunlight, high temperature, humidity and contamination in a ventilated area.
  • Workplace controlsFollow the current SDS and site procedures for dust handling and personal protection.

Buyer questions

Food grade MKP FAQ

Is monopotassium phosphate the same as potassium dihydrogen phosphate?

Yes. Monopotassium phosphate, potassium dihydrogen phosphate and monobasic potassium phosphate identify KH2PO4. For food use, specify INS/E340(i), CAS 7778-77-0 and the required food standard.

How is food grade MKP different from fertilizer MKP 0-52-34?

They can share the same chemical formula, but fertilizer grade is controlled and labeled for plant nutrition. Food grade requires food-additive identity, appropriate impurities, traceability, packing and applicable food documents. An NPK certificate does not qualify a food ingredient.

Is MKP acidic or alkaline?

MKP is the acidic potassium orthophosphate. JECFA specifies pH 4.2–4.7 for a 1% solution. Actual formulation pH depends on concentration and the full buffer, mineral and acid system.

Does the supplied specification meet JECFA?

Not as written: the supplied lead limit is 5 mg/kg versus JECFA's 4 mg/kg maximum, and several JECFA identity/quality fields are absent. Request a source-specific grade and COA that meet the selected standard.

What details are needed for an MKP quotation?

State food grade, intended application, target pH, potassium/phosphorus or K2O/P2O5 basis, specification, particle/solution requirements, quantity, packing, destination, Incoterm and documents.

Substantive content review: 2026-08-22 · Independent identity and specification reference: FAO/WHO JECFA.

Related products and application guides

Continue the MKP selection

MKP Fertilizer Grade

Use the separate agricultural page for 0-52-34, fertigation and crop-nutrition intent.

Specification-led sourcing

Request a food grade MKP quote

Identify the food-grade standard and mineral basis so the response is not confused with fertilizer MKP.

  • Food or fermentation application and target pH
  • Potassium/phosphorus or K2O/P2O5 reporting basis
  • Benchmark specification, particle and solution requirements
  • Quantity, packing, destination, Incoterm and documents

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