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Food leavening phosphate · E341(i) / INS 341(i)

Food Grade Monocalcium Phosphate Monohydrate (MCP)

Source calcium dihydrogen phosphate monohydrate for qualified bakery leavening, dough systems and food formulations. Specify CAS 10031-30-8, neutralizing value, reaction profile and particle requirements—not “MCP” alone.

Monohydrate CAS
10031-30-8
Formula
Ca(H2PO4)2·H2O
Supplied Ca range
15.9–17.7%*
Reference MOQ
500 kg*

*Commercial source reference; the signed source specification and methods must be reconfirmed.

Glass sample vessel labelled monocalcium phosphate MCP mono
Labelled MCP mono sample vessel.
Identity lockedMonohydrate CAS 10031-30-8
Leavening matchedNeutralizing value and gas timing required
Specification auditedOCR and method conflicts are disclosed
Supply reference25 kg bag; 23 MT / 20' FCL*

Product identity

What is food grade monocalcium phosphate monohydrate?

Monocalcium phosphate monohydrate (MCP or MCPM), standardized as calcium dihydrogen phosphate, is the hydrated acidic calcium phosphate Ca(H2PO4)2·H2O. JECFA identifies the monohydrate as CAS 10031-30-8 under INS 341(i).

JECFA lists buffering, firming, sequestrant, leavening, dough-conditioning, texturizing, yeast-food and nutrient functions. In chemical leavening, water brings MCP and bicarbonate into reaction, releasing carbon dioxide; production success depends on the exact neutralizing and gas-release profile.

Prevent grade and URL confusion

Food MCP monohydrate, anhydrous MCP and feed MCP

The abbreviation is shared across different hydration forms, coated leavening grades and animal-nutrition products. Formula alone does not qualify food use or predict reaction timing.

This page

Food MCP monohydrate

CAS 10031-30-8

Primary intent: food-grade identity, fast leavening evaluation and the supplied monohydrate-aligned calcium specification.

Separate food URL

Food anhydrous MCP / AMCP

CAS 7758-23-8

Anhydrous chemistry is separate. A slow-acting AMCP is commonly a specially coated/treated grade; “anhydrous” alone does not prove slow reaction.

Separate industry

Feed-grade MCP

Animal nutrition intent

Feed phosphorus/calcium, digestibility, fluorine, particle and registration requirements do not qualify material for food processing.

Receiving control: purchase description, label, lot, specification and COA must all identify the same hydration form and food-grade source. Do not release material using an agricultural or feed certificate.

Bakery performance—not a commodity assay alone

Neutralizing value and reaction timing

Neutralizing value (NV) expresses the mass of sodium bicarbonate neutralized by 100 parts of leavening acid. An industry reference commonly gives MCP monohydrate NV around 80, but the contractual value and method must come from the exact offered grade.

Acid–bicarbonate balance

Use the certified NV to calculate a starting ratio. Then adjust only after measuring finished-product pH, taste, color and residual alkalinity/acidity.

Early gas release

Uncoated MCP monohydrate is generally screened as a fast-acting acid. Track gas loss during mixing, transfer and bench hold before the structure sets.

Blended acid systems

Where oven-stage gas is needed, MCP can be evaluated with a slower leavening acid. Calculate each acid from its own NV and confirm total reaction by bake testing.

Grade variables

Particle size, coating/treatment, moisture, temperature, water availability, batter viscosity and ingredient order can shift the apparent reaction profile.

Do not publish a universal dosageNV is a stoichiometric starting tool, not a finished formula. Flour, cocoa, dairy solids, acids, salts and process conditions also consume or contribute acidity and change gas retention.

Application-specific screening

Where food grade MCP is evaluated

These are technical screening paths, not universal permissions or guaranteed outcomes.

Baking powder and dry premixes

Set NV, gas-release split, particle compatibility, segregation, humidity protection and shelf reaction. Test after the intended packaging and storage period.

Cakes, pancakes and short-hold batters

Evaluate early aeration, bench time, specific volume, cell structure, symmetry, crumb, color, pH and flavor under the actual mix and bake curve.

Cookies, biscuits and crackers

Measure spread, surface, color, texture and residual taste. Reaction balance can affect browning and dough handling as well as lift.

Mineral and other food systems

Where used for nutrient, buffering or firming functions, calculate calcium and phosphorus from certified composition and test solubility, sensory and complete-formula labeling.

Commercial sheet under technical audit

Supplied MCP specification: usable fields and unresolved conflicts

The source table contained OCR errors and mixed or undefined methods. It is shown transparently for qualification, not as a claim of JECFA conformity or a signed sales specification.

Ca range15.9–17.7%Matches JECFA monohydrate assay
Food identityINS 341(i)Exact source still required
Packing*25 kgCommercial reference
Loading*23 MTReference per 20' FCL
Supplied MCP commercial limits and audit decision
FieldSupplied / normalized valueAudit decision
AppearanceWhite crystalline powder or flake crystalsDoes not mirror JECFA “crystals, granules or granular powder”; confirm exact grade
Calcium (as Ca)15.9–17.7%Matches JECFA monohydrate assay; supports monohydrate—not anhydrous—identity
P2O550.0–52.5% (normalized from OCR “P₄O₆”)Basis and method unresolved; verify against signed original before use
CaO19.0–24.8%Broad range is not consistently derived from the stated Ca range; clarify reporting basis
IdentificationPositiveRequire separate calcium and phosphate methods
Arsenic≤0.0003% (=3 mg/kg)Matches JECFA maximum numerically
Fluoride≤0.0001% (=1 mg/kg)Much tighter than JECFA 50 mg/kg; likely needs OCR/unit verification
Heavy metals (as Pb)≤0.0015% (=15 mg/kg)Legacy aggregate parameter; not a replacement for named elements
Lead≤0.0005% (=5 mg/kg)Does not meet JECFA maximum of 4 mg/kg
Cadmium / mercuryEach ≤0.0001% (=1 mg/kg)Commercial fields; confirm destination limits and methods
“Loss on ignition”≤1.0%Method label conflicts with JECFA: monohydrate LOD ≤1% at 60°C/3 h; anhydrous LOI 14.0–15.5% at 800°C/30 min
“Loss on heating”≤17.0%Method and hydration interpretation unresolved
Clarity / carbonate / dissociable saltsPassProvide sample preparation, endpoint and source standard

Current publication decision: do not claim JECFA conformity

Lead exceeds the JECFA reference, the loss tests conflict, and key identity/purity methods are missing. Obtain the signed original and a source-specific offer meeting the selected standard before approval.

JECFA reference

Monohydrate: Ca 15.9–17.7%, LOD ≤1% at 60°C for 3 h; both forms: fluoride ≤50, arsenic ≤3 and lead ≤4 mg/kg, plus identity tests.

Review the JECFA MCP monograph

Missing leavening fields

Request NV with method, reaction-rate profile, particle distribution, bulk density, moisture behavior, slurry pH, insolubles, microbiology where required, shelf life and coated/uncoated status.

Bench-to-line approval

How to qualify MCP in a bakery system

  1. 1

    Lock the identity

    Require food-grade monohydrate, CAS 10031-30-8, source standard, label, signed specification and lot traceability.

  2. 2

    Balance from certified NV

    Calculate the starting bicarbonate ratio from the offered grade, while accounting for other formula acids and alkaline ingredients.

  3. 3

    Measure reaction timing

    Use matched water, temperature, mixer and hold time to track early and total gas release—not only final assay.

  4. 4

    Run product trials

    Compare volume, cells, symmetry, spread, color, pH, texture and taste against the approved benchmark.

  5. 5

    Stress the dry blend

    Test humidity, packaging, storage time, segregation and premature acid–bicarbonate reaction.

  6. 6

    Set receiving controls

    Agree identity, Ca assay, impurities, NV/reaction, particle distribution and COA fields with methods and change control.

Storage and handling

Protect hygroscopic MCP and premixes

  • Exclude moistureKeep approved bags sealed, dry and protected from puncture, contamination and humid air.
  • Use source conditionsThe supplied guidance says cool, dry, ventilated storage below 30°C; confirm shelf life and limits in the current specification.
  • Premix stabilityControl humidity and packaging after blending with bicarbonate to reduce premature reaction and activity loss.

Appearance and handling references

MCP powder and pallet reference

White powder in a glass dish labelled monocalcium phosphate MCP
Existing powder image
Wrapped pallet of paper bags secured with green straps near a forklift
Pallet handling reference

Buyer questions

Food grade MCP FAQ

Is this page for monohydrate or anhydrous MCP?

This URL now primarily covers food grade monocalcium phosphate monohydrate, CAS 10031-30-8. Bespring has a separate page for anhydrous MCP, CAS 7758-23-8, to prevent hydration-form and search-intent confusion.

Is MCP always a fast-acting leavening acid?

Uncoated MCP monohydrate is generally screened as fast acting, but the actual profile depends on grade, particle size, treatment/coating, moisture and process. Commercial coated anhydrous MCP can be designed for slower release, so request reaction data.

What is neutralizing value?

NV is the parts by mass of sodium bicarbonate neutralized by 100 parts of leavening acid. An industry reference commonly lists about 80 for MCP monohydrate, but purchasing and formulation must use the certified value for the offered grade.

Does the supplied specification meet JECFA?

Not as written. The supplied lead limit is 5 mg/kg versus JECFA's 4 mg/kg maximum, loss-test labels conflict and several methods are undefined. A corrected source-specific specification is required.

What should an MCP RFQ include?

State food-grade monohydrate, CAS 10031-30-8, target standard, NV and reaction profile, particle size, bakery application and process, quantity, 25 kg packing/pallet needs, destination, Incoterm and certificates.

Substantive content review: 2026-08-22 · Independent identity/specification reference: FAO/WHO JECFA · Leavening reference: American Society of Baking.

Related grade and system pages

Continue MCP qualification

Anhydrous MCP

Use the separate CAS 7758-23-8 page for anhydrous or coated AMCP requirements.

Food Grade DCP

Compare a different calcium phosphate identity and function; DCP is not a leavening substitute.

Feed Grade MCP

Use the animal-nutrition page for feed phosphorus, calcium and registration intent.

Identity- and performance-led sourcing

Request a food grade MCP monohydrate review

Include the exact identity and leavening method so the offer is not confused with anhydrous or feed-grade MCP.

  • Monohydrate CAS 10031-30-8 and food standard
  • Neutralizing value, reaction profile and particle requirements
  • Formula/process, hold time and finished-product targets
  • Quantity, packing, pallets, destination, Incoterm and documents

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