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Bespring Chemical

Food grade polyol · D-glucitol · CAS 50-70-4

Food Grade Sorbitol

Food-grade sorbitol (D-glucitol) is a polyol sweetener and humectant for confectionery, bakery and other suitable food systems. Compare powder and liquid grades by D-sorbitol content and reporting basis, including dry solids where applicable. Ask Bespring for the specification matching your formulation and destination requirements.
Crystalline identity
INS / E420(i)
Syrup identity
INS / E420(ii)
Formula (D-sorbitol)
C6H14O6
Offered specification
Confirm with sales
CAS
50-70-4 for D-sorbitol
Food grade sorbitol powder sample in a glass dish
Powder sample shown for reference. Liquid grades require a separate composition and handling specification.

Product image · confirm grade and packaging when ordering

State crystalline or syrup, solids/composition target, application, quantity and destination.

Form firstCrystalline and syrup RFQs are separated

Specification-ledComposition and methods must be source-specific

Application reviewMoisture, texture and sweetness tested together

Batch evidenceRequest current specification and COA

Product identity

What is food grade sorbitol?

Sorbitol, also called D-glucitol, is a polyol used in foods as a sweetener, humectant, bulking agent, texturizer, stabilizer and sequestrant. The JECFA sorbitol monograph identifies INS 420(i), CAS 50-70-4, with formula C6H14O6 and molecular mass 182.17 g/mol. These identifiers refer to D-sorbitol, not a complete syrup composition.

Sorbitol syrup is a separate food-additive identity, INS 420(ii). The JECFA sorbitol syrup specification describes a glucose-syrup hydrogenation product containing D-sorbitol, D-mannitol and other hydrogenated saccharides. Confirm composition and identity from the offered specification: dissolving sorbitol in water alone is not sufficient to identify an E420(ii) syrup.

Procurement snapshot

Standard name
Sorbitol / D-glucitol
CAS
50-70-4 for D-sorbitol
D-sorbitol molecular mass
182.17 g/mol
Crystalline appearance
White hygroscopic powder, crystals, flakes or granules
Commercial form
Crystalline or aqueous syrup—confirm
Specification
Request current grade-specific limits and methods

The decisive purchasing choice

Crystalline sorbitol vs. sorbitol syrup

Compare identity, composition and handling together. “Sorbitol 70% solution” and “non-crystallizing sorbitol” are commercial descriptions that need a defined solids basis and saccharide profile, not substitutes for a specification.

E420(i) / INS 420(i)

Crystalline sorbitol

Choose a dry form when water addition is undesirable or when dry blending, particle behavior and dissolution are important.

  • Confirm D-sorbitol and total glycitols on an anhydrous basis
  • Specify powder, crystal, granule or required particle-size range
  • Evaluate flow, caking, dust, dissolution and blend segregation
  • Control moisture because crystalline sorbitol is hygroscopic

E420(ii) / INS 420(ii)

Sorbitol syrup

Choose an aqueous form when liquid handling and pre-dissolved solids fit the process. “70%” commonly refers to total dry substance, not automatically 70% pure D-sorbitol in the finished liquid.

  • Confirm total solids and sorbitol on the stated dry or as-is basis
  • State crystallizing or non-crystallizing requirement where relevant
  • Review mannitol, reducing sugars and other polyols/saccharides
  • Evaluate viscosity, pumping, temperature and microbiological controls

Before selecting a grade: ask sales to confirm available form, additive identity, composition, particle size or liquid-handling properties, and the applicable specification. A crystallizing/non-crystallizing description is grade-specific; check its test conditions.

Function-led application screening

Where sorbitol performance must be tested

Sorbitol contributes more than sweetness. Changing form or replacing sucrose by weight can alter water, total solids, texture, freezing behavior and process conditions.

Chewing gum and confectionery

Screen bulk, sweetness, moisture retention and crystallization behavior. Cooling sensation is relevant when solid sorbitol dissolves during consumption; do not assume a pre-dissolved syrup gives the same effect. Test chew or bite, surface condition, stickiness and stability in the finished product.

Bakery, fillings and icings

Evaluate softness and moisture retention alongside dough/batter water, bake loss, browning, filling migration, stickiness and shelf texture. Syrup water must be included in the formulation balance.

Frozen and chilled desserts

Assess freezing-point response, solids, sweetness, overrun, ice-crystal development and melt behavior. Validate with the full sugar, stabilizer and milk-solids system.

Liquid foods and preparations

For a permitted liquid-food application, check clarity, viscosity, taste, pH compatibility and microbial control. Humectancy does not establish microbiological shelf stability. Confirm whether the selected syrup profile remains stable at storage and processing temperatures.

Claims are formulation- and market-specificThe presence of sorbitol alone does not substantiate “sugar-free,” “reduced sugar,” “low calorie,” dental or diabetes-related claims. Review the complete formulation and destination rules. U.S. 21 CFR 184.1835 sets food-category conditions and a consumption-based laxative-warning requirement; these are regulatory conditions, not recommended recipe levels.

Independent standard reference

JECFA reference for crystalline sorbitol E420(i)

The selected fields below are JECFA reference requirements, not Bespring commercial guarantees or batch results. Agree the source-specific specification and methods before purchase, then compare the batch COA with those agreed limits. Assay, identity and food-use permission are separate checks.

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Selected JECFA crystalline sorbitol reference fields
FieldJECFA referencePurchasing interpretation
Total glycitols≥97.0% on anhydrous basisSeparate total glycitols from D-sorbitol; specify chromatographic method
D-sorbitol≥91.0% on anhydrous basisConfirm HPLC method and anhydrous versus as-supplied basis
FormWhite hygroscopic powder, crystalline powder, flakes or granulesState required physical form and particle behavior
SolubilityVery soluble in water; slightly soluble in ethanolRun dissolution testing in the actual process
Melting range88–102°CIdentity reference, not a process guarantee

Crystalline sorbitol source

The monograph specifies assay by liquid chromatography, water by Karl Fischer, and separate lead, nickel, reducing-sugar and total-sugar tests. Request corresponding results; a total heavy-metals entry cannot replace individual element tests.

Open the JECFA crystalline sorbitol monograph

Sorbitol syrup source

The JECFA syrup monograph specifies ≥99.0% hydrogenated saccharides and ≥50.0% D-sorbitol on the anhydrous basis. Neither percentage is the syrup solids concentration. Request dry substance, water, composition and reporting basis separately; these standard values are not the offered grade specification.

Open the JECFA sorbitol syrup record

Build a usable purchasing specification

Sorbitol purchasing checklist

Request grade-specific criteria with methods, units and a document revision. A representative COA assists initial review; the supplied lot needs its own results. Confirm packaging, shelf life and delivery terms in the offer rather than assuming one format applies to both powder and syrup.

01

Fix identity and basis

Crystalline E420(i) or syrup E420(ii); total solids; D-sorbitol and total glycitols/polyols; dry-basis versus as-is reporting; crystallizing profile if applicable.

02

Set analytical limits

Reducing sugars and total sugars with glucose-equivalent basis; mannitol/other polyols; water method; pH with concentration/temperature; sulfated ash or stated residue method; individual lead, nickel and other required impurities. Karl Fischer water is not loss on drying.

03

Define physical behavior

Powder particle size, bulk density and flow, or syrup color/clarity, refractive index, density and viscosity at a stated temperature. A Brix or refractive-index reading requires a validated product-specific correlation; it does not measure D-sorbitol purity by itself.

04

Verify food and logistics scope

Microbiological criteria where applicable, allergen/origin declarations, valid site certificates, packing, shelf life, storage, quantity, Incoterm and destination.

Document set: request the current signed specification/TDS, SDS, representative COA and batch COA. Confirm document availability. Kosher, Halal, food-safety or other certificates require the exact product, site and validity period; company certification alone does not establish sorbitol coverage. For U.S. use, 21 CFR 184.1835 incorporates an FCC specification. A JECFA result alone is not proof of meeting that incorporated standard.

Formulation decision

Do not treat sorbitol as a one-to-one sucrose replacement

A technically sound trial separates sweetness from bulk, water management, texture and freezing behavior.

  1. 1

    Define the job

    State the target sweetness, water activity/moisture, solids, texture, shelf response and process constraints.

  2. 2

    Select the form

    Account for the water in syrup or the dissolution and particle behavior of crystalline material.

  3. 3

    Rebalance the system

    Adjust water and other sweeteners, bulking agents or stabilizers using measured rather than assumed equivalence.

  4. 4

    Validate over shelf life

    Measure sensory profile, texture, crystallization, migration, microbial stability and packaging interaction under intended conditions.

Storage and handling

Protect the selected sorbitol form

  • Crystalline materialKeep the specified packaging tightly closed and protect hygroscopic material from moisture, contamination and damage.
  • SyrupFollow source instructions for storage temperature, pumping and hygiene; viscosity and crystallization behavior can be temperature-sensitive.
  • Receiving controlsMatch product name, form, lot, label, seal, COA and shelf-life status before releasing material.

Buyer questions

Food grade sorbitol FAQ

Is sorbitol powder the same as sorbitol 70% solution?

No. Powder requires a dry-material specification; a liquid also requires its water and composition profile. Ask what “70%” measures: dry substance and D-sorbitol assay are different. Confirm whether the liquid is a sorbitol solution or an E420(ii) syrup under the applicable specification.

What is the difference between E420(i) and E420(ii)?

E420(i) identifies sorbitol. E420(ii) identifies sorbitol syrup, a preparation containing D-sorbitol and other hydrogenated saccharides/polyols. Physical form alone does not establish the identity; confirm the composition, standard and reporting basis of the exact offered product.

Which sorbitol form is better for confectionery or bakery?

Choose by the process. Powder makes particle size, flow, blending and dissolution relevant. Syrup adds water and requires suitable liquid handling. Compare sweetness, moisture, texture and crystallization in the complete formulation; neither is a one-to-one sucrose replacement.

Does non-crystallizing sorbitol mean it can never crystallize?

Treat the description as grade-specific behavior under stated conditions. Request the saccharide profile and storage/handling instructions, and test temperature cycles, concentration changes and formulation compatibility. Do not assume indefinite stability from the product name.

Are total glycitols, total solids and D-sorbitol assay the same?

No. Total solids describe dry material in a liquid. Total glycitols and D-sorbitol describe different compositional measures. Compare values only with the stated analytical method and dry or as-supplied basis; refractive index alone does not establish D-sorbitol purity.

Can sorbitol substantiate sugar-free or diabetes claims?

No. Ingredient identity alone cannot substantiate a finished-food nutrition or health claim. Review the full formulation, destination-market criteria and required sweetener or consumption warnings. Sorbitol use must also satisfy the conditions for the intended food category.

What should a sorbitol RFQ include?

Specify the form and additive identity, required food standard, solids and D-sorbitol reporting basis, application and process, particle size or liquid-handling needs, and critical test limits. Include quantity, packaging, destination, Incoterm, delivery requirements and requested TDS, SDS, COA and certificates.

Content updated: 2026-10-05 · Independent references: FAO/WHO JECFA and U.S. eCFR.

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Maltitol

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Erythritol

Compare a crystalline polyol with a different sweetness, cooling and moisture profile.

Form-specific sourcing

Request a food grade sorbitol quote

Identify the exact form and reporting basis so sales can screen a relevant source instead of returning a generic “sorbitol” offer.

  • Crystalline E420(i) or syrup E420(ii)
  • Solids, sorbitol/polyol basis and crystallizing profile
  • Application and critical physical/analytical limits
  • Quantity, packing, destination, Incoterm and documents

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Form & analytics information

Product documents

Request documents

Tell us your grade and destination market so we can confirm which documents are available for your order.

An external reference is not a batch certificate or a Bespring product specification. NIHS — D-Sorbitol ↗